Product ID:Z-6020 SILANE
MSDS Date:02/23/1988
FSC:8030
NIIN:00N015472
MSDS Number: BKQGN

DOW CORNING CORP

SOUTH SAGINAW ROAD
MIDLAND, MI 48686
US

Emergency Phone: 517-496-5900

Info Phone: 517-496-6000

Preparer: JACK L SHENEBERGER

Cage: 5D028

DOW CORNING CORP

AUBURN, MI 48611 US

Telephone: 517-496-4388

Cage: 71984

ETHYLENEDIAMINE (SARA III)

CAS: 107-15-3

RTECS: KH8575000

Fraction By Weight: <1%

OSHA PEL 10 PPM

ACGIH TLV: S, 10 PPM; 9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ETHYLENEDIAMINE,N-(3-(TRIMETHOXYSILYL)PROPYL)- (AMINOETHYL

CAS: 1760-24-3

RTECS: KV7400000

Fraction By Weight: >99%

OSHA PEL 200PPM;250PPM STEL,S

ACGIH TLV: 200PPM;250PPM STEL,S

FOR METHYL ALCOHOL, FORMED ON EXPOSURE TO WATER OR

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE: DIRECT CONT MAY BURN EYES, IRRIT
SEV/PERM INJURE DEPENDING ON EXPOS. SKIN: A SINGLE RELATIVELY SHORT
EXPOS (LESS THAN 24 HRS) IRRIT. RPTD/PRLNGD CONT (24 TO 48 HRS)
IRRIT SERIOUSLY, MAY BURN MILD LY. OVEREXP MAY INJURE INTERNALLY IF
ABSORBED. RPTD CONT MAY CAUSE ALLER SKIN SENSIT. INHAL: VAPS (SEE
EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: MAY IRRIT NOSE & THROAT SERIOUSLY &
MAY CAUSE DROW, NERV SYS DEPRESS, & UNCON. DEGREE OF INJURY WILL
DEPEND ON CONC & DURATION OF EXPOS. HIGH CONC FOR RPTD PRLNGD EXPOS
MAY CAUSE ALLERGIC SE NSIT. ORAL: SM AMTS MAY CAUSE BLINDNESS, EVEN
DEATH. COMMENTS: ETHYLENE DIAMINE MAY BE BOTH SKIN & RESP (SEE SUPP
DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES: IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES.
GET MD IMMED. SKIN: IMMEDIATELY WIPE OFF AND FLUSH WITH WATER FOR
15 MINUTES. GET MED ATTN IF ILL EFFECTS DEVELOP. INHAL: REMOVE TO
FRESH AI R. GET MED ATTN IF ILL EFTS PERSIST. ORAL: GET IMMED MED
ATTN. COMMENT: TREAT AS CAUSTIC BURN.

Flash Point Method:CC
Flash Point:120F,49C
Extinguishing Media:WATER FOG, CO*2, DRY CHEMICAL, FOAM, OTHER.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:HAZARDOUS NO*X FORM.

Spill Release Procedures:USE ABSORBENT MATERIAL TO COLLECT AND CONTAIN
FOR SALVAGE OR DISPOSAL. REMOVE ALL SOURCES OF IGNITION AND WEAR
PROPER PROTECTIVE EQUIPMENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP CONTAINER CLOSED AND AWAY FROM
WATER, HEAT, SPARKS, AND OPEN FLAME.
Other Precautions:STATIC ELEC MAY ACCUMULATE AND CREATE A FIRE HAZARD.
GROUND FIXED EQUIP. BOND & GROUND TRANSFER CONTAINERS & EQUIP. PROD
EVOLVES METHANOL WHEN EXPSD TO WATER/HUMID AIR. PROVIDE VENT DURING
USE/USE NIO SH/MSHA APPRVD AIR-SUPPLIED (SUPP DATA)

Respiratory Protection:NIOSH/MSHA APPROVED AIR-SUPPLIED OR
SELF-CONTAINED RESPIRATOR UNLESS LOCAL EXHAUST VENT IS ADEQ OR AIR
SAMPLING DATA EXPOSURES ARE WITHIN TLV & PEL GUIDELINES.
Ventilation:LOCAL EXHAUST: RECOMMENDED. MECHANICAL (GENERAL):
RECOMMENDED.
Protective Gloves:RUBBER OR PLASTIC GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES.(SEE SUPP DATA)
Other Protective Equipment:IMPERVIOUS PROTECTIVE CLOTHING: APRONS,
BOOTS, ETC.
Work Hygienic Practices:WASH IMMEDIATELY UPON ANY DETECTABLE CONTACT.
Supplemental Safety and Health
EFTS OF OVEREXP: SENSITIZER TO SUSCEPTIBLE INDIV. OTHER PREC: OR SCBA.
REMOVE GROSS AMT OF ANY CHEM FROM SKIN AS SOON AS PRACTICAL,
ESPECIALLY BEFORE EATING/SMOKING. AVOID BRTHING VAPORS & EYE & SKIN
CONTACT. USE ONLY W/ADEQUATE VENT. DO NOT TAKE INTERNALLY. EYE
PROT: MAY ADD FULL LENGTH FACE SHIELD TO GOGG .

HCC:V4
Boiling Pt:B.P. Text:>300F,>149C
Vapor Pres:<5
Spec Gravity:1.02
Evaporation Rate & Reference:LESS THAN 1 (ETHER = 1)
Solubility in Water:REACTS
Appearance and Odor:AMINE ODOR, LIQUID, STRAW COLORED.

Stability Indicator/Materials to Avoid:YES
OXIDIZING MATERIAL CAN CAUSE A REACTION.
Stability Condition to Avoid:REACTS WITH WATER, ACIDS, ETC., LIBERATING
METHANOL. AVOID EXPOSURE UNTIL READY TO USE.
Hazardous Decomposition Products:NO*X, SIO*2, CO*2, AND TRACES OF
INCOMPLETELY BURNED CARBON PRODUCTS.

Waste Disposal Methods:DOW CORNING SUGGESTS THAT ALL LOCAL, STATE, &
FEDERAL REGS CONCERNING HLTH & POLLUTION BE REVIEWED TO DETERMINE
APPROVED DISP PROC. CONTACT DOW CORNING IF THERE ARE ANY DISP
QUESTIONS.

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.